New glowing particles are supposed
to be less toxic; © Ya-Ping Sun
The carbon-based quantum dots show less potential for toxicity and environmental harm and have the potential to be less expensive than metal-based quantum dots, the scientists say. This could lead to applications such as improved biological sensors, medical imaging devices and tiny light-emitting diodes (LEDs).
"Carbon is hardly considered to be a semiconductor, so luminescent carbon nanoparticles are very interesting both fundamentally and practically," says study leader Ya-Ping Sun, Ph.D., a chemist at the Clemson University. "It represents a new platform for the development of luminescent nanomaterials for a wide range of applications."
Researchers have known for some time that carbon nanoparticles, due partly to their enormous surface area, have unusual chemical and physical properties quite different from their bulk form. Using nanoparticles produced from graphite, Sun and his associates demonstrated that when these carbon nanoparticles are covered with special polymers, they glow brightly when exposed to light, behaving as tiny light bulbs. The dots glow continuously as long as a light source is present, they say.
The scientists believe that this photoluminescence may be due to the presence of "pockets" or holes on the surface of the carbon dots that trap energy. The polymer coating acts as a "molecular band-aid," enabling light emission from the inside of the polymer casing, they say. Scientists believe that metal-based quantum dots emit light by a somewhat different mechanism.
The two-sided polymer coating allows researchers to attach antibodies or other labeling materials to the carbon dot, says Sun. This could lead to improved dyes for medical imaging and also the development of sensors that light up in the presence of a target, such as anthrax or even food-borne pathogens.
COMPAMED.de; Source: American Chemical Society