Chemists in The College of Arts and Sciences have figured out how to synthesize nanomaterials with stainless steel-like interfaces. Their discovery may change how the form and structure of nanomaterials are manipulated, particularly those used for gas storage, heterogeneous catalysis and lithium-ion batteries.
Until now, scientists have used many wet-chemical approaches—collectively known as colloidal synthesis—to manipulate reactions in which metallic ions form alloys at the nanoscale. Here, metal nanoparticles are typically 2 to 50 nanometers in size and have highly unique properties, including various colors, high reactivity and novel chemistry.
Mathew M. Maye and Wenjie Wu are part of a growing team of international chemists and materials scientists devising new ways to alter the size, shape and composition of nanoparticles.
“At SU, we have developed a new synthetic pathway to tailor the internal microstructure of nanomaterials,” says Maye, whose research spans inorganic chemistry, catalysis, materials science, self-assembly and biotechnology.
Maye’s approach begins with a pre-synthesized iron nanoparticle core. After synthesizing the core in its crystalline metallic form, he and Wu chemically deposit thin shells of chromium onto the iron. When the "core/shell" nanoparticles are exposed to high temperatures, they anneal. Moreover, the iron and chromium diffuse into one another, forming an iron-chromium alloy shell. Thus, the "core/alloy" product has an interface similar to some forms of stainless steel.
Since stainless steel is known for its resistance to oxidation, the big challenge for Maye and Wu has been finding out how nanoparticles cope during this process. “We’ve discovered that nanoparticles exhibit a unique behavior when oxidized,” he says. “A thin, iron-chromium oxide shell forms, leaving behind an unoxidized iron core. Even more interesting is the fact that a void forms, separating the core from the shell. This phenomenon is known in materials science as Kirkendall Diffusion, or Vacancy Coalescence."
This kind of work, he adds, would not be possible without high-resolution electron microscopy, X-ray diffraction and magnetic measurements. Although “core/alloy” fabrication is a new approach, it may allow for more diverse forms of alloy nanomaterials.
COMPAMED.de; Source: The College of Arts and Sciences