Strontium barium manganite’s
properties come from its
manganese atoms (purple sphere);
© 2012 Yasujiro Taguchi
An electric field can displace the cloud of electrons surrounding each atom of a solid. In an effect known as polarisation, the cloud centers move away slightly from the positively charged nuclei, which radically changes the optical properties of the solid. Materials that can maintain this polarisation, even when the external electric field is removed, are known as ferroelectrics and they could provide a novel route to higher-density memory devices.
“The function of ferroelectric materials is much expanded if they are also magnetic, and if there is a strong coupling between polarisation and magnetisation,” explains Yasujiro Taguchi from the RIKEN Advanced Science Institute in Wako. Taguchi and his colleagues and several other Japanese research institutes, recently demonstrated experimentally that the material strontium barium manganite ((Sr,Ba)MnO3) has this rare combination of properties1.
Previous experimental studies on (Sr,Ba)MnO3 did not identify any signs of the ferroelectricity promised by theoretical simulations. The problem was an insufficient ratio of barium to strontium atoms: conventional crystal growth techniques had produced material with only a maximum ratio of 1:4. Taguchi therefore developed a new two-stage growth technique that enabled them to increase the barium content to 50 percent. By comparing the properties of crystals with different levels of barium content, they identified a transition to a ferroelectric state at a content ratio of between 40 and 45 percent.
Strontium barium manganite has a so-called perovskite crystal arrangement, which is characterised by a repeating cubic structure. Manganese atoms are located at the center of the crystal and oxygen atoms are situated in the middle of each of the six sides. Either a strontium or a barium atom sits on each corner of the cube. The spin, or rotation, of an electron in the manganese ions makes the crystal magnetic. Ferroelectricity arises because the manganese ions are displaced slightly from the center of the cube. “Therefore the manganese ions are responsible for both polarisation and magnetism and thus a strong coupling between the two emerges,” explains Taguchi.
Materials that are both ferroelectric and have magnetic properties are called multiferroics. The multiferroic materials identified so far have either strong coupling between electricity and magnetism but small polarisation, or large polarisation with weak coupling. “We have now discovered a multiferroic material that has both,” says Taguchi. “These properties are necessary requirements if multiferroic materials are to be applied to devices. One possible example is low-power-consumption memory devices.”
COMPAMED.de; Source: Riken, Japan