Colours representing energy intensity:
excitons absorb laser light and emit
energy at various frequencies
The technique manipulates light energy and wave patterns to reveal subtle behaviour, such as correlated oscillations of two objects. Such correlations are important because they may allow researchers to more accurately predict the emission frequencies produced by an optoelectronic device based on its structure and semiconductor materials.
The method was developed originally by other researchers years ago for probing couplings between spinning nuclei as an indicator of molecular structure, and it led to a Nobel prize; more recently, scientists have been trying to use it to study vibrations in chemical bonds. The JILA, a joint institute of the National Institute of Standards and Technology and the University of Colorado at Boulder, team is the first to show the approach offers new insights into electronic properties of semiconductors. The use of light as a precision tool to manage electronic behaviour could lead to improved optoelectronic devices.
In the JILA technique, a sample made of thin layers of gallium arsenide is hit with a continuous series of three near-infrared laser pulses lasting just 100 femtoseconds each. Trillions of electronic structures called excitons are formed. They consist of "excited" electrons and the "holes" they leave behind as they jump to higher energy vibration patterns.
By changing the timing of the laser pulses and analyzing the wave patterns of the light and exciton oscillations, the scientists figured out how to produce and identify correlations between absorption and emission of light from the material. The presence or absence of correlations can be seen in a computer plot of the frequency and wave pattern of the absorbed and emitted light. Correlations are revealed as a pair of similar butterfly-shaped plots.
COMPAMED.de; Source: National Institute of Standards and Technology (NIST)